Hypervalent siloxane derivatives. An alternative to Stille and Suzuki couplings

Authors
DeShong, P Handy, CJ Mowery, ME
Citation
P. Deshong et al., Hypervalent siloxane derivatives. An alternative to Stille and Suzuki couplings, PUR A CHEM, 72(9), 2000, pp. 1655-1658
Citations number
20
Categorie Soggetti
Chemistry
Journal title
PURE AND APPLIED CHEMISTRY
ISSN journal
00334545 → ACNP
Volume
72
Issue
9
Year of publication
2000
Pages
1655 - 1658
Database
ISI
SICI code
0033-4545(200009)72:9<1655:HSDAAT>2.0.ZU;2-L
Abstract
Siloxane methodology is extended to couplings with iodo- and bromoanilines, hindered arylbromides, and substituted siloxanes as substrates. Additional ly, initial studies with 5-bromoindole and other heteroaromatics suggest th at the siloxane-mediated cross coupling methodology will also be applicable in these systems.