We report on sub-10 femtosecond time-resolved optical dynamics in polycarba
zolyldiacetylene blended in a polyethylene matrix which is a prototype of s
ingle chain systems. Transmission difference data reveal an ultrafast kinet
ics which is assigned to the rapid internal conversion taking place followi
ng photoexcitation. Oscillations in the time-dependent traces are assigned
to impulsive stimulated resonant Raman scattering, based on the comparison
with cw Raman data. (C) 2001 Elsevier Science B.V. All rights reserved.