We offer a new interpretation of photoexcitations in trans-polyacetylene an
d polydiacetylene-4BCMU. Based on the results of picosecond photoinduced ab
sorption and resonant Raman scattering, we postulate that breather excitons
may be the primary species photogenerated in these, and perhaps, other con
jugated polymers. (C) 2001 Elsevier Science B.V. All rights reserved.