Angular-dependent reflectivity techniques are employed to probe the optical
structure of microcavities containing a passive spacer layer, and also a f
luorescent polymer. For the fluorescent polymer, we used the polymer poly(9
,9-dioctylfluorene) (PFO), which was deposited between a dielectric and an
aluminium mirror. The reflectivity spectra exhibit a strong polarisation de
pendence with the cavity mode energy and photon linewidths of the cavity mo
de different for the TE (transverse electric) and TM (transverse magnetic)
polarisations. We find that as the cavity mode is moved away from the centr
e of the dielectric mirror stop-band, the difference between the energy of
the TE and TM modes grows. This results in a significant splitting of up to
110 meV between the TE and TM polarisations detected at large angle. We in
vestigate this effect by varying the energy of the cavity mode with respect
to the centre of the mirror stop-band. Results are analysed using a transf
er-matrix model. Photoluminescence emission from the PFO containing microca
vity was also measured. We find a splitting between TE and TM modes, which
is also manifested in the photoluminescence (PL) emission. This allows cont
rol of polarisation from an isotropic film, presenting a new method to cont
rol exciton emission. (C) 2001 Elsevier Science B.V. All rights reserved.