M. Bouroushian et al., Structure and properties of CdSe and CdSexTe1-x electrolytic deposits on Ni and Ti cathodes: influence of the acidic bath pH, THIN SOL FI, 381(1), 2001, pp. 39-47
The structural, morphological and photoelectrochemical features of coherent
CdSe and CdSexTe1-x thin film semiconductors, prepared by cathodic electro
deposition from an acid sulfate solution, were investigated. In particular,
the effect of deposition potential on the properties of layers grown onto
Ti and Ni substrates, in connection with the electrolyte acidity within the
bath pH interval [2.2, 1.6], was studied. As verified by X-ray diffraction
(XRD), scanning electron microscopy (SEM), reflectance and photoelectroche
mical cell (PEC) tests, the preparation method renders compact semiconducti
ve films, presenting a remarkably intense in the case of CdSe/Ni(111) cubic
structure, without any post-thermal treatment. The passive surface of Ti i
s associated with weaker texture; however, deposits on Ti generally exhibit
better photoelectrochemical behavior, under similar preparation conditions
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