Synthesis of bridged binuclear titanocene compounds - Crystal structure ofCl2Ti[(C5H4)(C5H4)(Me)Si-Si(Me)(C5H4)(C5H4)]TiCl2 center dot PhMe

Authors
Thiele, KH Gerstner, P Somoza, F
Citation
Kh. Thiele et al., Synthesis of bridged binuclear titanocene compounds - Crystal structure ofCl2Ti[(C5H4)(C5H4)(Me)Si-Si(Me)(C5H4)(C5H4)]TiCl2 center dot PhMe, Z ANORG A C, 627(1), 2001, pp. 28-30
Citations number
9
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
1
Year of publication
2001
Pages
28 - 30
Database
ISI
SICI code
0044-2313(200101)627:1<28:SOBBTC>2.0.ZU;2-E
Abstract
Starting from Cp-2(Me)Si-Si(Me)Cp-2 1 the complexes X2Ti[(C5H4)(C5H4)(Me)Si -Si(Me)(C5H4)(C5H4)]TiX2 (X = Cl (2a); X - Me (3)) were synthesized. The co mpounds were characterized by means of their H-1- and C-13-n.m.r. and MS-sp ectra. The crystal structure of 2a . PhMe was determined.