Synthesis, characterization, crystal structure, and hybrid DFT computationof antimony(III) chloride diazide, SbCl(N-3)(2)

Authors
Klapotke, TM Noth, H Schutt, T Warchold, M
Citation
Tm. Klapotke et al., Synthesis, characterization, crystal structure, and hybrid DFT computationof antimony(III) chloride diazide, SbCl(N-3)(2), Z ANORG A C, 627(1), 2001, pp. 81-84
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
1
Year of publication
2001
Pages
81 - 84
Database
ISI
SICI code
0044-2313(200101)627:1<81:SCCSAH>2.0.ZU;2-S
Abstract
SbCl(N-3)(2) was synthesized by the reaction of two equivalents of sodium a zide with SbCl3 in CH2Cl2. The structure of the compound was determined by X-ray structure determination. SbCl(N-3)(2) crystallizes in the monoclinic space group C2/c with a = 11.694(4), b = 7.751(4) and c = 12.241(5) Angstro m, beta = 100.45(1)degrees, with 8 formula units per unit cell. The SbCl(N- 3)(2) molecules show interactions to form chains. The frequencies obtained by Raman and infrared spectroscopy were assigned to the normal modes of the SbCl(N-3)(2) molecules in comparison with computational results.