Dispersing emissive dopants into luminescent polymers is an effective appro
ach to enhance luminescence and to tune emission color in organic light-emi
tting devices incorporating polymer films. However, the carrier trapping ef
fect due to emissive dopants often causes deterioration of electrical chara
cteristics. In this letter, we show that, by introducing a graded doping pr
ofile to match the carrier recombination zone in the doped polymer, the car
rier trapping, and the deterioration of electrical characteristics can be m
inimized while the enhancement in efficiency maintains. The finite-source d
ye-diffusion thermal transfer is used to produce graded doping profiles int
o a luminescent polymer. The effectiveness of this approach has been demons
trated in both single-layer and heterostructure devices incorporating doped
polymers. (C) 2001 American Institute of Physics.