A disilanyl dianion and a silyl dianion from a stable silylene

Authors
West, R Schmedake, TA Haaf, M Becker, J Mueller, T
Citation
R. West et al., A disilanyl dianion and a silyl dianion from a stable silylene, CHEM LETT, (1), 2001, pp. 68-69
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
1
Year of publication
2001
Pages
68 - 69
Database
ISI
SICI code
0366-7022(20010105):1<68:ADDAAS>2.0.ZU;2-F
Abstract
The stable silylene, N.N'-di-t-butyl-1,3-diaza-2-sila-2-ylidene, is reduced by Na/K or C8K first to a disilanyl dianion and then to a silyl dianion. B oth of these species can be derivatized by reaction with hydroxy compounds or with chlorotrimethylsilane.