Dichalcogenane derivatives of methylenedithio(ethylenedithio)tetrathiafulvalene (MET) and a derived metallic cation-radical salt with screwed donor stacks

Authors
Yamada, J Mangetsu, T Akutsu, H Nakatsuji, S Nishikawa, H Ikemoto, I Kikuchi, K
Citation
J. Yamada et al., Dichalcogenane derivatives of methylenedithio(ethylenedithio)tetrathiafulvalene (MET) and a derived metallic cation-radical salt with screwed donor stacks, CHEM LETT, (1), 2001, pp. 86-87
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
1
Year of publication
2001
Pages
86 - 87
Database
ISI
SICI code
0366-7022(20010105):1<86:DDOM>2.0.ZU;2-I
Abstract
The synthesis of the dichalcogenane derivatives of MET, (1,3-dioxan-2-yl)me thylenedithio(ethylenedithio)tetrathiafulvalene (DOA-MET) and (1.3-dithian- 2-yl)methylenedithio(ethyl-enedithio)tetrathiafulvalene (DTA-MET), and the preparation of their charge-transfer (CT) materials are investigated to exp lore new organic metals. The resulting (DOA-MET)(3)AuI2 salt exhibits weak metallic conducting behavior, and has screwed donor stacks.