At room temperature, the reaction of dibenzoyl peroxide with metallic coppe
r powder in the presence of pyridine affords the copper(II) complex [Cu(C5H
5N)(2) (H2O)-(C6H5COO)(2)]. Crystal is monoclinic, M-r = 483.002, space gro
up Cc with parameters: a = 6.078(4), b = 15.879(4), c = 23.091(3) Angstrom,
beta = 97.61(2)degrees, V = 2209.1(2) Angstrom (3), Z = 4, D-c = 1.464g/cm
(3), mu = 10.279 cm(-1), F(000) = 996,. R = 0.031, R-w = 0.036, 1595 reflec
tions with I greater than or equal to 3 sigma (I) were considered to be obs
erved. Each copper( II) ion is coordinated by two monodentate benzoate liga
nds, two pyridines and one water molecule. The complex is also characterize
d by its IR, XPS and thermal properties.