Separation of sulfonamides by capillary electrochromatography

Authors
Citation
S. Dube et Rm. Smith, Separation of sulfonamides by capillary electrochromatography, CHROMATOGR, 53(1-2), 2001, pp. 51-56
Citations number
29
Categorie Soggetti
Chemistry & Analysis","Spectroscopy /Instrumentation/Analytical Sciences
Journal title
CHROMATOGRAPHIA
ISSN journal
00095893 → ACNP
Volume
53
Issue
1-2
Year of publication
2001
Pages
51 - 56
Database
ISI
SICI code
0009-5893(200101)53:1-2<51:SOSBCE>2.0.ZU;2-5
Abstract
The dual separation mechanism exhibited by capillary electrochromatography is demonstrated by the simultaneous separation of sulfonamides as charged a nd neutral species over a pH range of 2.5 to 6.9. The neutral sulfonamides were separated according to the difference in their hydrophobicities while charged components were separated by the differences in their electrophoret ic mobilities. The limitation of capillary electrochromatography for acidic components was also examined.