The effective diffusion coefficient of radon was determined in polymer
/silicate gels and clay suspension used as sealing materials in enviro
nmental protection. On the basis of the experimental findings, it was
concluded that both materials drastically decrease the convective mass
transport in porous media. Simultaneously, the effective diffusion co
efficient was reduced significantly. Thus, the radon flux might be dec
reased by 5 to 6 orders of magnitude in porous systems originally havi
ng gas or low water saturation by injection of gel-forming materials o
r placement of clay suspensions. At high water saturation, however, th
e diffusion transport of radon can be slightly restricted in consolida
ted and unconsolidated porous media. The laboratory studies may firmly
allow us to conclude that hydrogels and clay suspensions are prospect
ive candidates in an integrated environmental technology to be used fo
r restriction of radon migration in subsurface regions.