Fe9O3(OC2H5)(21)center dot C2H5OH - A new structure type of an uncharged iron(III) oxide-alkoxide cluster

Citation
M. Veith et al., Fe9O3(OC2H5)(21)center dot C2H5OH - A new structure type of an uncharged iron(III) oxide-alkoxide cluster, EUR J INORG, (2), 2001, pp. 367-368
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
2
Year of publication
2001
Pages
367 - 368
Database
ISI
SICI code
1434-1948(200102):2<367:FDC-AN>2.0.ZU;2-7
Abstract
A new nona iron(III) oxide-alkoxide cluster has been prepared by the treatm ent of FeCl3 with three equivalents of sodium ethoxide. The molecule is the first example of a neutral iron(III) alkoxide cluster based on OEt ligands and shows a paramagnetic moment of 13.4(1) mu (B) at 293 K in the solid st ate.