Synthesis of a substituted bi[cyclohepta-3,5(3 ',5 ')-dienyl]: A possible building block for domino Diels-Alder reactions

Citation
M. Sander et Ev. Dehmlow, Synthesis of a substituted bi[cyclohepta-3,5(3 ',5 ')-dienyl]: A possible building block for domino Diels-Alder reactions, EUR J ORG C, (2), 2001, pp. 399-404
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
2
Year of publication
2001
Pages
399 - 404
Database
ISI
SICI code
1434-193X(200101):2<399:SOASB'>2.0.ZU;2-P
Abstract
A versatile 13-step synthesis of 1,1'-dimethoxy-4,4',5,5' tetrakis(trimethy lsilyloxy)bicyclohepta-3,3',5,5'-dienyl (11) is described. 11 represents a potential building block for the construction of polycyclic cage compounds through domino Diels-Alder and pincer reactions.