Ceric ion initiation of methyl methacrylate from poly(glycidyl azide)-diol

Authors
Arslan, H Eroglu, MS Hazer, B
Citation
H. Arslan et al., Ceric ion initiation of methyl methacrylate from poly(glycidyl azide)-diol, EUR POLYM J, 37(3), 2001, pp. 581-585
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN POLYMER JOURNAL
ISSN journal
00143057 → ACNP
Volume
37
Issue
3
Year of publication
2001
Pages
581 - 585
Database
ISI
SICI code
0014-3057(200103)37:3<581:CIIOMM>2.0.ZU;2-A
Abstract
Polymerization of methyl methacrylate initiated by eerie ammonium nitrate i n combination with poly(glycidyl azide)-diol was investigated in aqueous ni tric acid. Poly(methyl methacrylate)-b-poly(glycidyl azide) copolymer was o btained. Block copolymer yield was increased using tetrabutyl ammonium hydr ogen sulphate as a surfactant. The effect of nitric acid, eerie ions and di ol concentration on the block copolymer yield was investigated. Block copol ymers were characterized using GPC,H-1-NMR, FTIR, DSC, TGA and fractional p recipitation methods. (C) 2001 Elsevier Science Ltd. All rights reserved.