Thermokinetic oscillations of the rate of radiation-induced cryochemical solid-phase chain reactions

Authors
Citation
Dp. Kiryukhin, Thermokinetic oscillations of the rate of radiation-induced cryochemical solid-phase chain reactions, HIGH ENERG, 35(1), 2001, pp. 1-11
Citations number
32
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
HIGH ENERGY CHEMISTRY
ISSN journal
00181439 → ACNP
Volume
35
Issue
1
Year of publication
2001
Pages
1 - 11
Database
ISI
SICI code
0018-1439(200101/02)35:1<1:TOOTRO>2.0.ZU;2-6
Abstract
Data on the detection and the experimental and theoretical investigation of thermokinetic rate oscillations in cryochemical chain reactions induced by radiation (Co-60 gamma -rays) in a solid phase are surveyed. Such oscillat ory modes follow the general pattern and they are observed for different re actions (hydrobromination, polymerization, and copolymerization of ethylene ) in crystalline and glassy states both immediately in a gamma -radiation f ield and as a post effect upon heating of samples.