Influence of the inner coordination sphere on the Ru(III)-cyanamido ligand-to-metal charge transfer chromophore

Authors
Mosher, PJ Yap, GPA Crutchley, RJ
Citation
Pj. Mosher et al., Influence of the inner coordination sphere on the Ru(III)-cyanamido ligand-to-metal charge transfer chromophore, INORG CHEM, 40(3), 2001, pp. 550
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
3
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010129)40:3<550:IOTICS>2.0.ZU;2-J
Abstract
[Ru(bpy)(trpy)L]PF6 complexes, where trpy is 2,2':6',2 " -terpyridine, bpy is 2,2'-bipyridine, and L is a phenylcyanamido derivative, have been prepar ed and characterized. Spectroelectrochemistry permitted an analysis of the Ru(III)-cyanamido chromphore of these complexes. These results were compare d to those of the analogous pentaammineruthenium(III) complexes.