Square pyramidal dialkoxo-bound monooxo-vanadium(V) complex and its behavior in solution

Authors
Moon, M Pyo, M Myoung, YC Il Ahn, C Lah, MS
Citation
M. Moon et al., Square pyramidal dialkoxo-bound monooxo-vanadium(V) complex and its behavior in solution, INORG CHEM, 40(3), 2001, pp. 554
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
3
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010129)40:3<554:SPDMCA>2.0.ZU;2-N
Abstract
A mononuclear dialkoxo-bound monooxo-vanadium(V) complex, VO(acetylacetosal icylhydrazone)(OEt) 1, was synthesized and structurally characterized. In a chloroform solution, complex 1 exists in two forms. The major species is a monomeric form, as in the solid-state structure, and the minor species con verts to the monomeric form in the presence of a small amount of ethanol.