NMR evidence for benzodioxane structures resulting from incorporation of 5-hydroxyconiferyl alcohol into lignins of O-methyltransferase-deficient poplars
J. Ralph et al., NMR evidence for benzodioxane structures resulting from incorporation of 5-hydroxyconiferyl alcohol into lignins of O-methyltransferase-deficient poplars, J AGR FOOD, 49(1), 2001, pp. 86-91
Benzodioxane structures are produced in lignins of transgenic poplar plants
deficient in COMT, an O-methyltransferase required to produce lignin syrin
gyl units. They result from incorporation of 5-hydroxyconiferyl alcohol int
o the monomer supply and confirm that phenols other than the three traditio
nal monolignols can be integrated into plant lignins.