SPATIAL-ORGANIZATION IN THE A-]0 REACTION UNDER CONFINED-SCALE MIXING(B)

Citation
R. Reigada et al., SPATIAL-ORGANIZATION IN THE A-]0 REACTION UNDER CONFINED-SCALE MIXING(B), The Journal of chemical physics, 107(3), 1997, pp. 843-848
Citations number
31
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
107
Issue
3
Year of publication
1997
Pages
843 - 848
Database
ISI
SICI code
0021-9606(1997)107:3<843:SITARU>2.0.ZU;2-A
Abstract
We consider the kinetics of the two-dimensional, stoichiometric A+B--> O reaction under confined-scale turbulent mixing and concentrate on th e interplay between the kinetic patterns and the spatial organization of the system. We study the properties of the arising clusters and of the reaction zones, both in the presence and in the absence of mixing. We show that the two-point correlation function C-AB(r)=[c(A)(r'+r)c( B)(r')]/[c(A)(r)](2) is closely related to the effective reaction rate , while the functional form of the quartic correlation function Q(r,t) A)(r'+r,t)c(B)(r'+r.t)]/[c(A)(2)(r,t)c(B)(2)(r,t)] is connected to th e geometry of the reaction zones. We pay special attention to the occu rrence of time windows of fast (classical) concentration decay even wh en the reactants show strong segregation. (C) 1997 American Institute of Physics.