R. Reigada et al., SPATIAL-ORGANIZATION IN THE A-]0 REACTION UNDER CONFINED-SCALE MIXING(B), The Journal of chemical physics, 107(3), 1997, pp. 843-848
We consider the kinetics of the two-dimensional, stoichiometric A+B-->
O reaction under confined-scale turbulent mixing and concentrate on th
e interplay between the kinetic patterns and the spatial organization
of the system. We study the properties of the arising clusters and of
the reaction zones, both in the presence and in the absence of mixing.
We show that the two-point correlation function C-AB(r)=[c(A)(r'+r)c(
B)(r')]/[c(A)(r)](2) is closely related to the effective reaction rate
, while the functional form of the quartic correlation function Q(r,t)
A)(r'+r,t)c(B)(r'+r.t)]/[c(A)(2)(r,t)c(B)(2)(r,t)] is connected to th
e geometry of the reaction zones. We pay special attention to the occu
rrence of time windows of fast (classical) concentration decay even wh
en the reactants show strong segregation. (C) 1997 American Institute
of Physics.