M. Akatsuka et al., Delamination mechanism of high-voltage coil insulators made from mice flakes and thermosetting epoxy resin, J APPL POLY, 79(12), 2001, pp. 2164-2169
To clarify the delamination mechanism of high-voltage coil insulators made
from mica flakes and epoxy resin due to static mechanical stress, the relat
ionships between the shear strength of the insulator and the physical prope
rties of the component materials were studied. The mechanism of their delam
ination was thought to be either a lack of epoxy resin between the mica fla
kes, interface failure between the mica flakes and the epoxy resin, or clea
vage of the mica flakes. The first two mechanisms were discounted because t
he shear strength of the insulator was found to be independent of both the
contact angle of the corresponding liquid epoxy resin on the mica flakes an
d the critical surface tension of the epoxy resin. Furthermore, the shear s
trength of the model insulator was improved by using an epoxy resin with a
higher bending elastic modulus, implying that the delamination mechanism in
this system is the cleavage of mica flakes. Therefore, the epoxy resin sho
uld have a high elastic modulus to ensure high delamination resistance, tha
t is, the temperature to which the insulators are exposed should be lower t
han the glass transition temperature of the corresponding epoxy resin. Opti
cal microscope studies also supported these results. (C) 2001 John Wiley &
Sons, Inc.