THE BENDING VIBRATION OF FED2 AT 226 CM(-1), DETECTED BY FAR-INFRAREDLASER MAGNETIC-RESONANCE SPECTROSCOPY

Authors
KORSGEN H EVENSON KM BROWN JM
Citation
H. Korsgen et al., THE BENDING VIBRATION OF FED2 AT 226 CM(-1), DETECTED BY FAR-INFRAREDLASER MAGNETIC-RESONANCE SPECTROSCOPY, The Journal of chemical physics, 107(3), 1997, pp. 1025-1027
Citations number
19
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
107
Issue
3
Year of publication
1997
Pages
1025 - 1027
Database
ISI
SICI code
0021-9606(1997)107:3<1025:TBVOFA>2.0.ZU;2-Z
Abstract
We report the first gas phase observation of a bending vibration in an open shell molecule by far-infrared laser magnetic resonance. The spe ctrum is due to FeD2; its observation shows that rovibrational transit ions can be detected with such a spectrometer. The molecule was produc ed in the reaction between deuterium atoms and iron pentacarbonyl. FeD 2 has a linear (5) Delta ground state and shows the effects of Renner- Teller coupling in the excited vibrational (010) level. (C) 1997 Ameri can Institute of Physics.