Electric field induced instabilities at liquid/liquid interfaces

Citation
Zq. Lin et al., Electric field induced instabilities at liquid/liquid interfaces, J CHEM PHYS, 114(5), 2001, pp. 2377-2381
Citations number
32
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
114
Issue
5
Year of publication
2001
Pages
2377 - 2381
Database
ISI
SICI code
0021-9606(20010201)114:5<2377:EFIIAL>2.0.ZU;2-R
Abstract
External electric fields were used to amplify thermal fluctuations at the i nterface between two thin liquid films. Similar to the results shown previo usly for the enhancement of fluctuations at the polymer/air interface, inte rfacial fluctuations having a well-defined wavelength were enhanced with a characteristic growth rate. A simple theoretical framework to describe the experimental observations is presented. Both experiment and model calculati on show a substantial reduction in feature size as a result of the change i n surface/interfacial energy when going from the thin film to the bilayer c ase. Experimentally, features develop nearly 50 times faster for the bilaye rs in comparison to the polymer/air case. These results point to a simple r oute by which the nanoscopic feature can be easily and rapidly produced or replicated. (C) 2001 American Institute of Physics.