We have studied the effect of p-GaN:Mg cap layers which were grown using MO
CVD with various flow rates of Cp2Mg on the turn-on voltage of p-n junction
LED. Before fabricating the LEDs, the p-GaN:Mg/sapphire (0 0 0 1) epilayer
s grown with various flow rates of Cp2Mg were evaluated in order to investi
gate the characteritics of each layer. We investigated the dependence of ac
ceptor concentration on the flow rate of dopant source. The Van der Pauw te
chnique, double crystal X-ray diffractometry (DCXRD:) and photoluminescence
(PL) were used to characterize their crystallographic, electrical and opti
cal properties. As the incorporation of Mg in GaN/sapphire (0 0 0 1) epitax
y increases, the resistivity of the epilayers increases abruptly without di
scontinuity due to the increase of the much uncracked Mg-H complex. In spit
e of the continuous increase of Mg incorporation, the hole concentration of
the epilayers increases at first and then decreases from a certain amount
of Mg incorporation. As a result of the increase of the hole concentration,
the emission intensity of the layers in the :PL spectra at room temperatur
e increases at first and then decreases from a certain flow rate of Cp2Mg.
After full evaluation of each p-GaN:Mg epitaxial layer, LED structures of t
he p-n junction type were grown by the growth of these cap layers and fabri
cated. Next, they were characterized by I-V measurement in order to investi
gate the effect of p-GaN : Mg cap layers on the turn-on voltage of the LED
structures. The current of the LEDs at forward bias mode becomes low as the
resistivity of p-GaN : Mg cap layer increases. However, the LED fabricated
by the cap layer which has the highest hole concentration shows the greate
st current value. While the turn-on voltage of pn junction LED fabricated b
y p-GaN:Mg having high hole concentration above 1 x 10(17)/cm(3) depends on
the hole concentration of each p-GaN:Mg cap layer, the voltage of the devi
ces fabricated by the cap layer having low hole concentration below 1 x 10(
17)/cm(3) is nearly dependent on the electrical resistivities of each p-GaN
:Mg. (C) 2001 Elsevier Science B.V.. All rights reserved.