The paper reviews research activities on fluoride grasses in France over th
e last 10 years. Glass compositions for industrial applications as well as
new glasses from academic research are presented. They include heavy-metal
fluoride glasses, fluorochloride glasses and oxyfluoride glasses. Besides p
hysico-chemical properties, special attention is paid to the optical charac
teristics of heavy-metal fluoride glasses. They exhibit broader infrared tr
ansparency than oxides, which results in unique optical properties and appl
ications, especially in the fields of fiber lasers and optical amplifiers o
perating at wavelengths not accessible with silica. (C) 2001 Elsevier Scien
ce B.V. All rights reserved.