[(thf)(6)Ba-6(dmpz)(8){(OSiMe2)(2)O}(2)] (dmpz=3,5-dimethylpyrazolate): a molecule with six barium cations in a plane capped by two siloxane dianionsand framed by eight dmpz anions
A. Steiner et al., [(thf)(6)Ba-6(dmpz)(8){(OSiMe2)(2)O}(2)] (dmpz=3,5-dimethylpyrazolate): a molecule with six barium cations in a plane capped by two siloxane dianionsand framed by eight dmpz anions, J CHEM S DA, (3), 2001, pp. 219-221
Citations number
46
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
In the synthesis of barium 3,5-dimethylpyrazolate, silicone joint grease an
d cyclo-(Me2SiO)(4) are cleaved and two O(SiMe2O)(2)(2-) bidentate chelatin
g siloxane anions are coordinated above and below an unprecedented Ba-6(12-
) layer framed by eight sigma/pi coordinated pyrazolate anions.