Geometrical preferences of complexes of terpyridine N-oxide ligands: synthesis and crystal structures of nickel(II) with terpyridine 1,1',1 ''-trioxide, terpyridine 1,1 ''-dioxide and terpyridine 1-oxide

Citation
Aj. Amoroso et al., Geometrical preferences of complexes of terpyridine N-oxide ligands: synthesis and crystal structures of nickel(II) with terpyridine 1,1',1 ''-trioxide, terpyridine 1,1 ''-dioxide and terpyridine 1-oxide, J CHEM S DA, (3), 2001, pp. 225-227
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
3
Year of publication
2001
Pages
225 - 227
Database
ISI
SICI code
1472-7773(2001):3<225:GPOCOT>2.0.ZU;2-0
Abstract
[NiL2][ClO4](2) complexes (L = terpyridine 1,1',1 " -trioxide, terpyridine 1,1 " -dioxide and terpyridine 1-oxide) have been prepared and crystallogra phically characterised; data shows a predictable variation in ligand confor mation, such as facial or meridonal binding, which is in agreement with DFT calculations.