An open-framework phosphate oxalate of zinc, of composition [NH3(CH2)(3)NH3
][Zn-6(PO4)(4)(C2O4)], 1, has been synthesized, for the first time, employi
ng hydrothermal methods in the presence of ethylenediamine. The structure c
omprises a network of Zn(1)O-5, Zn(2)O-4, Zn(3)O-5 polyhedra and PO4 tetrah
edra connected through their vertices forming neutral layers bridged by the
oxalate units, giving one-dimensional channels. The presence of Zn in tetr
ahedral, trigonal-bipyramidal and square-pyramidal coordinations, and the f
ormation of neutral layers, are noteworthy features.