A zinc phosphate oxalate with phosphate layers pillared by the oxalate units

Citation
S. Neeraj et al., A zinc phosphate oxalate with phosphate layers pillared by the oxalate units, J CHEM S DA, (3), 2001, pp. 289-291
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
14727773 → ACNP
Issue
3
Year of publication
2001
Pages
289 - 291
Database
ISI
SICI code
1472-7773(2001):3<289:AZPOWP>2.0.ZU;2-W
Abstract
An open-framework phosphate oxalate of zinc, of composition [NH3(CH2)(3)NH3 ][Zn-6(PO4)(4)(C2O4)], 1, has been synthesized, for the first time, employi ng hydrothermal methods in the presence of ethylenediamine. The structure c omprises a network of Zn(1)O-5, Zn(2)O-4, Zn(3)O-5 polyhedra and PO4 tetrah edra connected through their vertices forming neutral layers bridged by the oxalate units, giving one-dimensional channels. The presence of Zn in tetr ahedral, trigonal-bipyramidal and square-pyramidal coordinations, and the f ormation of neutral layers, are noteworthy features.