A new reaction of 1-hydrosilatrane

Authors
Lukevics, E Ignatovich, L Golomba, L Popelis, J Belyakov, S
Citation
E. Lukevics et al., A new reaction of 1-hydrosilatrane, MAIN GR MET, 23(12), 2000, pp. 761-764
Citations number
34
Categorie Soggetti
Chemistry
Journal title
MAIN GROUP METAL CHEMISTRY
ISSN journal
07921241 → ACNP
Volume
23
Issue
12
Year of publication
2000
Pages
761 - 764
Database
ISI
SICI code
0792-1241(2000)23:12<761:ANRO1>2.0.ZU;2-Z
Abstract
It has been shown that 1-hydrosilatrane reacts with o-difluoromethoxybenzal doxime in refluxing xylene without any catalyst affording a new type of sil atranes - iminoxysilatrane. The first representative of them o-difluorometh oxybenzylideniminoxysilatrene (3) has been characterized by IR, H-1, C-13, F-19 and Si-29 NMR spectroscopy, mass-spectrometry, elemental and X-ray ana lyses. X-Ray crystallographic study indicates the presence of two independe nt molecules in the crystal with N-->Si bond length of 2.073(6) and 2.088(5 ) Angstrom.