A detailed mathematical analysis is presented to advance the current unders
tanding of the mechanics of milling operation in a planetary ball mill in t
erms of a global Cartesian reference space. The ab initio calculations have
identified the role of milling parameters in determining the condition of
detachment of the ball from the vial wall. The condition of an 'effective'
impact has been identified in terms of the vial-to-disk speed ratio. It eme
rges from the analysis that the role of velocity components of the ball at
the instant of its impact on the vial wall warrants proper consideration, b
ecause the tangential force determines the lower bound of the vial-to-disk
speed ratio conducive for effective transfer of impact energy to the powder
charge in the mill. Finally, a comparison of the experimental results of g
rain size reduction during milling of elemental Fe and Cu-Al powder blend w
ith the similar predictions of the present analysis demonstrates for the fi
rst time that elastic properties of the balls and vials play an important r
ole in determining the rate of structural refinement during ball milling. (
C) 2001 Elsevier Science B.V. All rights reserved.