Fabrication of LiCoO2 thin-film cathodes for rechargeable lithium microbatteries

Polycrystalline thin films of lithium cobalt oxide were grown by pulsed-las er deposition (PLD) technique. Films of LiCoO2 were deposited onto Si subst rates heated at temperature lower than 300 degreesC from a sintered composi te target (LiCoO2 + Li2O) irradiated with a Nd:YAG laser. The structural ch aracterizations of these films were carried out by X-ray diffraction and Ra man scattering spectroscopy, which probe the local environment of cations i n the LiCoO2 framework. Raman spectra of PLD LiCoO2 films were investigated as a function of various growth conditions as substrate temperature, parti al oxygen pressure in the deposition chamber, and target composition. PLD L iCoO2 films obtained with a polycrystalline morphology were successfully us ed as cathode materials in lithium microbatteries. The Li//LiCoO2 cells wer e tested by cyclic voltammetry and galvanostatic charge-discharge technique s in the potential range 2.0-4.2 V. Specific capacity as high as 195 mC cm( -2) mum was measured on polycrystalline films. (C) 2001 Elsevier Science B. V. All rights reserved.