Novel terpene-based chiral bis-alpha-aminooximes and the corresponding macrocycles: X-ray structure of a ring-fused 5,7-dioxa-1,4,8,11-tetraazacyclotrideca-3,8-diene derivative

Authors
Petukhov, PA Bagryanskaya, IY Gatilov, YV Tkachev, AV
Citation
Pa. Petukhov et al., Novel terpene-based chiral bis-alpha-aminooximes and the corresponding macrocycles: X-ray structure of a ring-fused 5,7-dioxa-1,4,8,11-tetraazacyclotrideca-3,8-diene derivative, MENDELEEV C, (6), 2000, pp. 209-210
Citations number
13
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436 → ACNP
Issue
6
Year of publication
2000
Pages
209 - 210
Database
ISI
SICI code
0959-9436(2000):6<209:NTCBAT>2.0.ZU;2-M
Abstract
The treatment of (+)-3-carene nitrosochloride with 1,2-diaminoethane result s in bis-alpha -aminoxime, which undergoes intramolecular cyclisation under phase-transfer conditions to yield an optically active macroheterocyclic c ompound with two carane moieties incorporated.