The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions

Authors
Zakharova, LY Valeeva, FG Kudryavtseva, LA Konovalov, AI
Citation
Ly. Zakharova et al., The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions, MENDELEEV C, (6), 2000, pp. 241-243
Citations number
20
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436 → ACNP
Issue
6
Year of publication
2000
Pages
241 - 243
Database
ISI
SICI code
0959-9436(2000):6<241:TKOSOP>2.0.ZU;2-B
Abstract
A 30-fold acceleration of the title reaction due to an increase in the acti vation entropy and activation enthalpy in the micellar pseudophase compared to ethylene glycol was found; Mg2+, Zn2+ and La3+ ions accelerate the solv olysis by factors of 5, 8 and 20, respectively.