New hybrid ditopic ligands containing fused phenanthroline and crown etherunits

Citation
Cr. Rice et al., New hybrid ditopic ligands containing fused phenanthroline and crown etherunits, NEW J CHEM, 25(2), 2001, pp. 185-187
Citations number
16
Categorie Soggetti
Chemistry
Journal title
NEW JOURNAL OF CHEMISTRY
ISSN journal
11440546 → ACNP
Volume
25
Issue
2
Year of publication
2001
Pages
185 - 187
Database
ISI
SICI code
1144-0546(2001)25:2<185:NHDLCF>2.0.ZU;2-Q
Abstract
Reaction of 5,6-dihydroxy-1,10-phenanthroline with various poly(ethylene)gl ycol-ditosylates affords, in good yield, a series of ligands in which a phe nanthroline binding site is attached to an adjacent crown ether unit; the N N chelating site may be coordinated to {Ru(bipy)(2)}(2+) units to afford [R u(bipy)(3)](2+) derivatives with pendant crown ether units, which can bind alkali metal ions.