Neighboring group participation by chromium in substitution reactions of (eta(6)-arene)tricarbonylchromium complexes

Authors
Merlic, CA Miller, MM
Citation
Ca. Merlic et Mm. Miller, Neighboring group participation by chromium in substitution reactions of (eta(6)-arene)tricarbonylchromium complexes, ORGANOMETAL, 20(3), 2001, pp. 373-375
Citations number
53
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
3
Year of publication
2001
Pages
373 - 375
Database
ISI
SICI code
0276-7333(20010205)20:3<373:NGPBCI>2.0.ZU;2-0
Abstract
(eta (6)-Arene)tricarbonylchromium complexes with leaving groups at the bet a- or gamma -positions undergo nucleo-philic substitution reactions with ne t retention of stereo-chemistry via neighboring group participation from th e coordinatively saturated chromium atom.