The appearance of additional states of an impurity under high doping levels
is discussed. On the basis of a Fermi level calculation, a model for the c
onductivity of heavily boron-doped diamond is proposed. This model allows o
ne to reproduce the temperature dependence of the conductivity and of the H
all coefficient for different impurity concentrations. The temperature depe
ndence of the conductivity was found to be connected with the coexistence o
f valence-hand and hopping conductivities in a wide temperature range. The
hopping conductivity takes place over the additional states of the boron im
purity.