Electrical conductivity of hexachlorocyclotriphosphazene and its derivatives

Citation
Vv. Vapirov et al., Electrical conductivity of hexachlorocyclotriphosphazene and its derivatives, RUSS J G CH, 70(7), 2000, pp. 1041-1045
Citations number
17
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
70
Issue
7
Year of publication
2000
Pages
1041 - 1045
Database
ISI
SICI code
1070-3632(200007)70:7<1041:ECOHAI>2.0.ZU;2-M
Abstract
A complex conductivity study was performed for the first time on hexachloro cyclotriphosphazene and its salt prepared by the reaction with 4-methylpyri dine N-oxide. Specific conductivity, activation energy, and dielectric cons tant were measured for the two compounds. A mechanism of electronic transpo rt was proposed, involving vacant d orbitals of the phosphorus atom.