Citation
Ab. Fel'Gendler et al., beta-acetyl(benzoyl)-beta-nitrostyrenes: Synthesis and reactions with CH acids, RUSS J G CH, 70(7), 2000, pp. 1087-1093
Citations number
20
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632
→ ACNP
Volume
70
Issue
7
Year of publication
2000
Pages
1087 - 1093
Database
ISI
SICI code
1070-3632(200007)70:7<1087:BSARWC>2.0.ZU;2-D
Abstract
beta -Keto-substituted beta -nitrostyrenes were synthesized by condensation
of benzaldehyde and its analogs with nitroacetone or nitroacetophenone. Re
actions of gem-acetyl(benzoyl)nitrostyrenes with a series of CH acids were
studied, and the products of nucleophilic addition reactions with malonic,
cyanoacetic, and acetaminomalonic esters were obtained. With acetylacetone,
along with linear addition products, a heterocyclization product was isola
ted, substituted dihydrofuran.