Interaction of nickel oxide with chlorine

Authors
Anufrieva, TA Derlyukova, LE Vinokurova, MV
Citation
Ta. Anufrieva et al., Interaction of nickel oxide with chlorine, RUSS J IN C, 46(1), 2001, pp. 16-19
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
1
Year of publication
2001
Pages
16 - 19
Database
ISI
SICI code
0036-0236(200101)46:1<16:IONOWC>2.0.ZU;2-M
Abstract
The interaction of nickel oxide with gaseous chlorine is studied from 200 t o 850 degreesC. The formation of nickel chloride begins at 350 degreesC. Be tween 400 and 700 degreesC, the process is accompanied by chlorine accumula tion in the solid and is controlled by the growth of NiCl2 nuclei. The chlo rination product, NiCl2, sublimes at temperatures above 750 degreesC. The r ate-controlling stage of chlorination is sublimation.