Synthesis and thermal stability of fluorinated graphite intercalation compounds of pentafluoropyridine

Authors
Paasonen, VM Grankin, VM Kozlova, SG Gabuda, SP
Citation
Vm. Paasonen et al., Synthesis and thermal stability of fluorinated graphite intercalation compounds of pentafluoropyridine, RUSS J IN C, 46(1), 2001, pp. 44-46
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
1
Year of publication
2001
Pages
44 - 46
Database
ISI
SICI code
0036-0236(200101)46:1<44:SATSOF>2.0.ZU;2-S
Abstract
The composition and physicochemical properties of a fluorinated graphite in tercalation compounds (FGICs) with pentafluoropyridine were studied by IR a nd NMR spectroscopies. X-ray powder diffraction, and elemental analysis. As found by mass spectrometry, the intercalation compound releases pentafluor opyridine in two steps: the first is observed between 313 and 483 K, and th e second sets in at similar to 590 K simultaneously with matrix decompositi on.