Reducing thermolysis of [Rh(NH3)(5)Cl][PdCl4]H2O

Authors
Korenev, SV Shubin, YV Belyaev, AV
Citation
Sv. Korenev et al., Reducing thermolysis of [Rh(NH3)(5)Cl][PdCl4]H2O, RUSS J IN C, 46(1), 2001, pp. 62-64
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
1
Year of publication
2001
Pages
62 - 64
Database
ISI
SICI code
0036-0236(200101)46:1<62:RTO[>2.0.ZU;2-F
Abstract
An efficient technique for synthesizing a double complex salt [Rh(NH3)(5)Cl ][PdCl4]H2O is developed. Thermal dissociation of this salt under inert and reducing atmospheres is studied. Various solid solutions of rhodium and pa lladium are the thermolysis products. Provisional data on the interaction o f these solid solutions with nitric acid are obtained.