Ethylenediammonium ethylenediaminetetraacetatobismuthate(III) hexahydrate:Synthesis and crystal structure

Authors
Davidovich, RL Logvinova, VB Ilyukhin, AB
Citation
Rl. Davidovich et al., Ethylenediammonium ethylenediaminetetraacetatobismuthate(III) hexahydrate:Synthesis and crystal structure, RUSS J IN C, 46(1), 2001, pp. 65-68
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
1
Year of publication
2001
Pages
65 - 68
Database
ISI
SICI code
0036-0236(200101)46:1<65:EEH>2.0.ZU;2-I
Abstract
Bismuth(III) ethylenediaminetetraacetate hexahydrate with protonated ethyle nediamine as a counterion ({H(2)En}[Bi(Edta)(H2O)](2). 4H(2)O) was synthesi zed; its crystal structure was determined. The complex {H(2)En}[Bi(Edta)(H2 O)](2). 4H(2)O is isostructural to its antimony analogue. The behavior of t he lone electron pair of the Sb3+ and Bi3+ cations in the isostructural com plexes is discussed.