Calculation of the coefficient of distribution of admixtures for the process of forming gas hydrates in sulfur hexafluoride

Citation
Vm. Vorotyntsev et al., Calculation of the coefficient of distribution of admixtures for the process of forming gas hydrates in sulfur hexafluoride, RUSS J PH C, 75(1), 2001, pp. 121-125
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
75
Issue
1
Year of publication
2001
Pages
121 - 125
Database
ISI
SICI code
0036-0244(200101)75:1<121:COTCOD>2.0.ZU;2-U
Abstract
A theoretical analysis of the possibility of an influence of the formation of gas hydrates on the efficiency of the fine purification of sulfur hexafl uoride was performed. The redistribution of the components of a gas mixture was characterized by the relative distribution coefficient K-21. As a resu lt of the purification, gas hydrates become enriched in sulfur dioxide (K-2 1 > 1) and depleted in nitrogen (K-21 < 1). Depending on the pressure of th e gas mixture, the distribution coefficient for carbon dioxide can be eithe r higher or lower than unity. The analysis performed shows that, under cert ain conditions, the phenomenon of formation of gas hydrates can be used for the fine purification of sulfur hexafluoride from a variety of admixtures.