Oxygen-induced surface structure of Nb(110)

The Nb(1 1 0) surface is investigated prior to and after thermal treatment in vacuum by in situ Auger electron spectroscopy, reflection high-energy el ectron diffraction, and scanning tunneling microscopy (STM) and spectroscop y. After Art sputtering a clean surface is obtained. Subsequent short annea ling at 1300 K gives rise to segregation of oxygen from the bulk to the sur face. The presence of oxygen induces a long-range ordered superstructure as inferred from the electron diffraction patterns in different azimuths. Thi s is confirmed by STM images which reveal a regularly arranged network of f inite chains rotated 5 degrees with respect to the Nb(1 1 1) directions. Th is orientation, the symmetry of the network, and the in-plane interatomic d istances measured by STM suggest that the superstructure is a precursor for the formation of an epitaxial f.c.c.-NbO(1 1 1) layer on Nb(1 1 0) with in -plane orientation NbO[1 0 (1) over bar] parallel to Nb[0 0 1] and NbO[1 (2 ) over bar 1]) parallel to Nb[1 (1) over bar 0]. (C) 2001 Elsevier Science B.V. All rights reserved.