Novel enantiomer-switching catalysts for asymmetric reductions and Michaelreactions

Citation
S. Narasimhan et al., Novel enantiomer-switching catalysts for asymmetric reductions and Michaelreactions, TETRAHEDR L, 42(4), 2001, pp. 719-721
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
4
Year of publication
2001
Pages
719 - 721
Database
ISI
SICI code
0040-4039(20010122)42:4<719:NECFAR>2.0.ZU;2-O
Abstract
The newly developed chiral ligands 1 and 2 show opposite enantioselectivity in prochiral ketone reduction and Michael addition reactions resulting in the production of both enantiomers of the products in good chemical and ena ntiomeric yield. (C) 2001 Elsevier Science Ltd. All rights reserved.