Excess properties for acetophenone plus butanols at 298.15 K

Citation
R. Riggio et al., Excess properties for acetophenone plus butanols at 298.15 K, CAN J CHEM, 79(1), 2001, pp. 50-53
Citations number
26
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
ISSN journal
00084042 → ACNP
Volume
79
Issue
1
Year of publication
2001
Pages
50 - 53
Database
ISI
SICI code
0008-4042(200101)79:1<50:EPFAPB>2.0.ZU;2-B
Abstract
Densities, viscosities, and refractive indexes of binary systems acetopheno ne + n-butanol, + sec-butanol, and + 2-methyl-1-propanol have been measured at 298.15 K and atmospheric pressure, over the whole composition range. Th e excess values of molar volume, viscosity, Gibbs free energy of activation of viscous flow, and internal pressure were calculated from experimental m easurements. Based on the variations of the excess functions with compositi on, conclusions about the molecular interactions in these kinds of mixtures were obtained.