A pH-stat test was used to assess extractability of inorganic sulfur compou
nds from fly ashes. The tests were performed in the pH range 3-11. Constant
pH values were maintained by addition of dilute nitric acid or sodium hydr
oxide solutions. The only inorganic sulfur-containing species identified in
the extracts was sulfate. The method showed excellent precision: relative
standard deviations of repeatability and reproducibility were in the ranges
4.67-8.68 % and 4.67-10.99 %, respectively.