Hydrogenation of 3-(dimethylamino)propionitrile over palladium catalysts

Authors
Krupka, J Pasek, J Navratilova, M
Citation
J. Krupka et al., Hydrogenation of 3-(dimethylamino)propionitrile over palladium catalysts, COLL CZECH, 65(11), 2000, pp. 1805-1819
Citations number
21
Categorie Soggetti
Chemistry
Journal title
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
ISSN journal
00100765 → ACNP
Volume
65
Issue
11
Year of publication
2000
Pages
1805 - 1819
Database
ISI
SICI code
0010-0765(200011)65:11<1805:HO3OPC>2.0.ZU;2-H
Abstract
Hydrogenation of 3-(dimethylamino)propionitrile over palladium catalysts wa s studied. Besides the expected amines, N,N,N'N'-tetramethylpropane-1,3-dia mine, N,N-dimethyl-N'-propylpropane-1,2-diamine, and N,N-bis[3-(dimethylami no)propyl]propylamine were found. Reaction pathways of their formation were discussed. Effects of reaction conditions, type of catalyst, and addition of ammonia or an amine into the charge on the hydrogenation selectivity wer e studied.