The reaction of beta-amino alcohols with 1,1 '-carbonyldiimidazole - Influence of the nitrogen substituent on the reaction course

Authors
Cutugno, S Martelli, C Negro, L Savoia, D
Citation
S. Cutugno et al., The reaction of beta-amino alcohols with 1,1 '-carbonyldiimidazole - Influence of the nitrogen substituent on the reaction course, EUR J ORG C, (3), 2001, pp. 517-522
Citations number
86
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
3
Year of publication
2001
Pages
517 - 522
Database
ISI
SICI code
1434-193X(200102):3<517:TROBAW>2.0.ZU;2-E
Abstract
The reaction of p-amino alcohols with 1,1'-carbonyldiimidazole in dichlorom ethane is affected by the size of the nitrogen substituent. 1,3-Oxazolidin- 2-ones are exclusively obtained from N-H, N-methyl and N-arylmethyl derivat ives. O-(1-Imidazolyl)carbonyl derivatives are formed as intermediates